PALAPALA PALAPALA

Wahi a ka UN GHS revision 8

Manaʻo: 1.0

Ka lā i hana ʻia: Iulai 15, 2019

Lā Hoʻoponopono: Iulai 15, 2019

PAUKU 1: Hoike

1.1GHS Mea hōʻike huahana

1.2 Nā ala ʻē aʻe o ka ʻike

1.3 Manaʻo ʻia ka hoʻohana ʻana i ka kemika a me nā kapu o ka hoʻohana ʻana

1.4Nā kikoʻī o ka mea hoʻolako

1.5Helu kelepona pilikia

PAUKU 2: Hoike pilikia

2.1 Ka hoʻokaʻawale ʻana o ka mea a i ʻole ka hui ʻana

Nā wai ʻaʻa ahi, Māhele 1

ʻona ʻino - Māhele 3, waha

ʻO ka ʻawaʻawa nui - Māhele 3, Dermal

ʻO ka ʻili ʻili, Māhele 2

ʻO ka ukiuki maka, Māhele 2

ʻO ka ʻawaʻawa nui - Māhele 2, Inhalation

ʻO ka ʻawaʻawa o ke kino i hoʻopaʻa ʻia - ʻike hoʻokahi, Māhele 3

He pōʻino i ke kaiapuni wai, no ka wā pōkole (Acute) – Māhele Acute 1

He pōʻino i ke kaiapuni wai, lōʻihi (Chronic) - Māhele Chronic 1

2.2GHS nā mea lepili, me nā ʻōlelo hoʻomalu

2.3 Nā pōʻino ʻē aʻe ʻaʻole i hopena i ka hoʻokaʻawale ʻana

ʻaʻohe ʻikepili i loaʻa

PAUKU 3: Ka hoʻohui ʻana/ka ʻike e pili ana i nā meaʻai

3.1Nā mea

PAUKU 4: Nā hana kōkua mua

4.1 Ka wehewehe ʻana i nā hana kōkua mua e pono ai

Ina inhaled

Ea hou, hoomaha. Kūlana hapa-kūpono. E kuhikuhi no ka mālama kino.

Ma hope o ka pili ʻana i ka ʻili

Wehe i nā lole i haumia. Holoi i ka ʻili me ka wai nui a i ʻole ka ʻauʻau. E kuhikuhi no ka mālama kino .

Mahope o ka pili maka

Holoi me ka wai nui no kekahi mau minuke (e wehe i nā leka pili inā hiki ke maʻalahi). E kiʻi koke no ka lāʻau lapaʻau.

Ma hope o ka ʻai ʻana

Holoi waha. MAI hooulu i ka luai. Hāʻawi i hoʻokahi a ʻelua paha kīʻaha wai e inu ai. E kuhikuhi no ka mālama kino .

4.2 ʻO nā hōʻailona koʻikoʻi nui / hopena, ʻeha a lohi

Wehe mai ka ERG Guide 131 [Nā wai hiki ke hoʻā ʻia - Toxic]: TOXIC; hiki ke make ke inhaled, inested or absorbed through ili. ʻO ka inhalation a i ʻole ka hoʻopili ʻana me kekahi o kēia mau mea e hoʻonāukiuki a puhi paha i ka ʻili a me nā maka. E hoʻopuka ke ahi i nā kinoea hoʻonāukiuki, ʻino a/a ʻona paha. Hiki i nā mahu ke hoʻonāwaliwali a ʻeha paha. Hiki ke hoʻohaumia i ka hoʻoheheʻe ʻana mai ke ahi a i ʻole ka wai dilution. (ERG, 2016)

4.3 Nā hōʻailona o ka mālama kino koke a me ka mālama kūikawā e pono ai, inā pono

Kokua mua koke: E hōʻoia i ka hoʻomaʻemaʻe pono ʻana. Inā ʻaʻole hanu ka mea maʻi, e hoʻomaka i ka hanu ʻana, ʻoi aku ka maikaʻi me kahi resuscitator koi-valve, ʻeke-valve-mask device, a i ʻole pocket mask, e like me ke aʻo ʻana. Hana CPR e like me ka mea e pono ai. E holoi koke i nā maka i haumia me ka wai kahe mālie. Mai hoʻoulu i ka luaʻi. Inā loa'a ka lua'i, e ho'omoe i ka mea ma'i i mua a i 'ole e kau ma ka 'ao'ao hema (ke po'o i lalo, inā hiki) no ka mālama 'ana i kahi alaloa hāmama a pale i ka mana'o. E noho mālie a mālama i ka wela kino maʻamau. Loaʻa i ka lāʻau lapaʻau. Ketones a me nā mea pili

PAUKU 5: Na hana kinai ahi

5.1 Hiki ke hoʻopau ʻia ka media hoʻopau

Inā he mea ahi a komo paha i ke ahi: Mai kinai i ke ahi ke ʻole hiki ke hoʻōki i ke kahe. E kinai i ke ahi me ka hoʻohana ʻana i ka lāʻau kūpono no ke ʻano ahi a puni. (ʻAʻole ʻā a ʻā paha ka waiwai ponoʻī me ka paʻakikī.) Hoʻolili i nā pahu i hoʻopilikia ʻia me ka nui o ka wai. E noi i ka wai mai kahi mamao e hiki ai. E hoʻohana i ka huʻa, kemika maloʻo, a i ʻole carbon dioxide. E mālama i ka wai kahe mai loko mai o nā ʻōpala a me nā kumu wai. Chloroacetone, paʻa

5.2 Nā pōʻino kikoʻī e puka mai ana mai ka kemika

Wehe mai ka ERG Guide 131 [Nā wai hiki ke ʻā - ʻawaʻawa]: HIGHLY FLAMMABLE: E hoʻā maʻalahi ʻia e ka wela, nā ʻulaʻula a i ʻole ke ahi. Hiki i nā mahu ke hana i nā hui pahū me ka ea. Hiki i nā mahu ke hele i ke kumu o ka ʻā a hoʻi i hope. ʻOi aku ke kaumaha o ka hapa nui o nā mahu ma mua o ka ea. E laha lākou ma ka ʻāina a hōʻiliʻili ma nā wahi haʻahaʻa a paʻa paha (nā ʻōpala, nā basements, nā pahu). Pahū ʻana i ka mahu a me nā mea ʻawaʻawa i loko o ka hale, waho a i ʻole i loko o nā ʻauwai. Hiki ke polymerize pahū nā mea i kapa ʻia me ka (P) ke hoʻomehana ʻia a i ʻole ke komo ʻana i ke ahi. Hiki ke hoʻomake ʻia ke ahi a i ʻole ka pahū ʻana o ka wai kahe. Hiki ke pahū nā pahu i ka wā i wela ai. ʻOi aku ka māmā o nā wai ma mua o ka wai. (ERG, 2016)

5.3 Nā hana pale kūikawā no nā mea puhi ahi

E hoʻohana i ka ehu wai, ka pauka, ka huʻa waiʻona, carbon dioxide. I ke ahi: mālama i nā pahu, a me nā mea ʻē aʻe, maʻalili ma ke kāpī ʻana me ka wai.

PAUKU 6: Nā hana hoʻokuʻu ulia pōpilikia

6.1 Hoʻomalu pilikino, nā lako pale a me nā kaʻina hana pilikia

Wehe i nā kumu puhi ahi. E haʻalele i kahi pilikia! E kūkākūkā me kahi loea! Palekana pilikino: kānana respirator no nā kinoea organik a me nā mahu i hoʻololi ʻia i ka neʻe ʻana o ka mea ma ka lewa. ʻO ka makani. E hōʻiliʻili i ka wai kahe i loko o nā pahu i uhi ʻia. E hoʻopaʻa i ke koena wai i ke one a i ʻole ka mea hoʻoheheʻe inert. A laila mālama a hoʻolei aku e like me nā kānāwai kūloko.

6.2 Ka mālama ʻana i ke kaiapuni

Wehe i nā kumu puhi ahi. E haʻalele i kahi pilikia! E kūkākūkā me kahi loea! Palekana pilikino: kānana respirator no nā kinoea organik a me nā mahu i hoʻololi ʻia i ka neʻe ʻana o ka mea ma ka lewa. ʻO ka makani. E hōʻiliʻili i ka wai kahe i loko o nā pahu i uhi ʻia. E hoʻopaʻa i ke koena wai i ke one a i ʻole ka mea hoʻoheheʻe inert. A laila mālama a hoʻolei aku e like me nā kānāwai kūloko.

6.3 Nā ʻano a me nā mea hana no ka hoʻopaʻa ʻana a me ka hoʻomaʻemaʻe

Nā noʻonoʻo kaiapuni – ʻāhuʻi ʻāina: Eli i lua, loko iʻa, loko, wahi paʻa e loaʻa ai ka wai a i ʻole nā ​​mea paʻa. /SRP: Inā hiki i ka manawa, pono e ho'opa'a 'ia nā lua, nā loko, nā pūnāwai, nā lua wai, a me nā wahi e pa'a ana me ka liner membrane hiki'ole ke ho'ololi. E hoʻomohu i ka wai nui me ka lehu lele, ka pauka sima, a i ʻole nā ​​mea hoʻoheheʻe kālepa. Chloroacetone, paʻa

PAUKU 7: Ka lawelawe a me ka waiho ana

7.1 E mālama pono i ka mālama ʻana

ʻAʻohe lapalapa e hāmama, ʻaʻohe kukuna ahi a ʻaʻole puhi. Ma luna aʻe o 35°C e hoʻohana i kahi ʻōnaehana paʻa, ea a me nā lako uila pahū. ʻO ka lawelawe ʻana ma kahi wahi maikaʻi. E ʻaʻahu i nā lole pale kūpono. Hōʻalo i ka pili ʻana me ka ʻili a me nā maka. E pale i ka hana ʻana o ka lepo a me nā aerosol. E hoʻohana i nā mea hana ʻole. Kāohi i ke ahi i hana ʻia e ka mahu hoʻolele electrostatic.

7.2 Nā kūlana no ka mālama pono ʻana, me nā mea like ʻole

E kūʻai wale inā paʻa. Pale ahi. Hoʻokaʻawale ʻia mai nā oxidants ikaika a me nā meaʻai a me nā meaʻai. E mālama i ka pōʻeleʻele. E kūʻai wale inā paʻa. Pale ahi. Hoʻokaʻawale ʻia mai nā oxidants ikaika, nā meaʻai a me nā meaʻai. E mālama i loko o ka pōʻeleʻele… Ma luna o 35 deg C e hoʻohana i kahi ʻōnaehana pani, ea, a me nā lako uila pahū.

PAUKU 8: Nā hoʻomalu hoʻolaha/pale pilikino

8.1 Nā ʻāpana hoʻomalu

Nā waiwai palena o ka Hōʻike Hana

TLV: 1 ppm e like me STEL; (ʻili)

Koiola palena waiwai

ʻaʻohe ʻikepili i loaʻa

8.2 Nā mana ʻenehana kūpono

E hōʻoia i ka pono o ka ea. Hana e like me ka hoʻomaʻemaʻe ʻoihana maikaʻi a me ka hana palekana. E hoʻonohonoho i nā puka ulia pōpilikia a me ka wahi hoʻopau pilikia.

8.3 Nā hana pale kanaka, e like me nā lako pale pilikino (PPE)

Pale maka/maka

E hoʻohana i ka pale maka a i ʻole ka pale maka i hui pū ʻia me ka pale hanu.

Pale ʻili

Nā mīkina lima pale. Nā lole pale.

Pale hanu

E hoʻohana i ka ventila, hoʻopau kūloko a i ʻole pale hanu.

Nā pōʻino wela

ʻaʻohe ʻikepili i loaʻa

PAUKU 9: Ka waiwai kino a me ke kemika a me na ano palekana

PAUKU 10: Pa'a a me ka hana hou

10.1 Ka hana hou

Hoʻopili mālie ka mea ma lalo o ka mana o ka mālamalama. Hoʻopuka kēia i ke ahi a pahū paha. Decomposes ma ka wela a me ke ahi.

10.2 Paʻa kemika

Huli i ka pōʻeleʻele a hoʻololi hou i ka ʻike lōʻihi i ka mālamalama, hiki ke hoʻopaʻa ʻia e 0.1% wai a i ʻole 1.0% calcium carbonate.

10.3 Hiki i nā hopena pōʻino

Hiki ke ʻā ʻia ke ʻike ʻia i ka wela a i ʻole ka lapalapa, a i ʻole nā ​​mea oxidizer. Huli ʻo CHLOROACETONE i ka pōʻeleʻele a hoʻopiʻi i ka resinifies i ka wā lōʻihi i ka mālamalama [Merck]. Hana ʻia kēia i loko o ka ʻōmole i ka wā e mālama ai no ʻelua mau makahiki ma kahi papa ma ke kukui ākea. He mau lā ma hope o ka hoʻoneʻe ʻia ʻana o ka ʻōmole, ua pahū [Ind. Eng. Nūhou 9: 184(1931)]. Hoʻokūpaʻa ʻia e ka hoʻohui ʻana o 0.1% wai a i ʻole 0.1% CaCO3.

10.4 Nā kūlana e pale aku ai

ʻaʻohe ʻikepili i loaʻa

10.5Nā mea kūpono ʻole

KĀMĀKĀKĀKĀ: Hoʻopau iā ia iho. Ua ʻeleʻele ʻo Chloroacetone i ka wā o ka mālama ʻana no ʻelua mau makahiki ma luna o ia iho i ke kukui ākea. He mau lā ma hope o ka hoʻoneʻe ʻia ʻana o ka ʻōmole chloroacetone, ua pahū. Ua polymerized ka chloroacetone i mea like me ka eleele, Ind. Eng. Nūhou 9: 184(1931). (REACTIVITY, 1999)

10.6Nā huahana decomposition weliweli

Ke hoʻomehana ʻia a palaho, hoʻopuka ʻo ia i nā uahi ʻona loa.

PAUKU 11: ʻIkepili toxicological

ʻinoʻino loa

• waha: LD50 Iole waha 100 mg/kg
• Inhalation: LC50 Inhalation iole 262 ppm/1 hola
• Dermal: ʻaʻohe ʻikepili i loaʻa

ʻO ka ʻili ʻino/ka ʻeha

ʻaʻohe ʻikepili i loaʻa

Poino nui ka maka

ʻaʻohe ʻikepili i loaʻa

Ka hanu a i ʻole ka ʻili o ka ʻili

ʻaʻohe ʻikepili i loaʻa

ʻO ka mutagenicity cell germ

ʻaʻohe ʻikepili i loaʻa

Carcinogenicity

ʻaʻohe ʻikepili i loaʻa

ʻO ka ʻawaʻawa hānau

ʻaʻohe ʻikepili i loaʻa

STOT-hoʻokahi hōʻike

Lachrymation. He mea hoʻonāukiuki loa ka mea i ka maka, ka ʻili a me ka ʻōpū hanu.

Hōʻike hou STOT

ʻaʻohe ʻikepili i loaʻa

Pilikia aspiration

Hiki ke loaʻa koke i kahi ʻino ʻino o ka ea i ka hoʻoheheʻe ʻana o kēia mea ma 20 ° C.

PAUKU 12: ʻIke pili kaiaola

12.1 ʻona

• ʻO ka ʻawaʻawa i ka iʻa: ʻaʻohe ʻikepili i loaʻa
• ʻAʻole i loaʻa ka ʻikepili i ka daphnia a me nā mea ʻē aʻe i loko o ka wai
• ʻAʻole i loaʻa ka ʻikepili
• ʻAiʻona i nā microorganism: ʻaʻohe ʻikepili i loaʻa

12.2 Ka hoʻomau a me ka degradability

ʻaʻohe ʻikepili i loaʻa

12.3 Hiki ke bioaccumulative

Ua helu ʻia kahi BCF o 3 i ka iʻa no 1-chloro-2-propanone(SRC), me ka hoʻohana ʻana i ka log Kow i manaʻo ʻia he 0.02(1) a me kahi hoʻohālikelike i loaʻa i ka regression (2). Wahi a kekahi papa helu (3), hōʻike kēia BCF i ka haʻahaʻa (SRC) no ka bioconcentration i nā mea ola wai.

12.4Ka neʻe ʻana ma ka lepo

Me ka hoʻohana ʻana i ke ʻano hoʻohālikelike hoʻolālā e pili ana i nā helu hoʻohui molecular (1), hiki ke koho ʻia ke Koc o 1-chloro-2-propanone he 5(SRC). Wahi a kekahi papa helu (2), ʻo kēia waiwai Koc i manaʻo ʻia he 1-chloro-2-propanone e manaʻo ʻia he kiʻekiʻe loa ka neʻe ʻana i ka lepo.

12.5 Nā hopena ʻino ʻē aʻe

ʻaʻohe ʻikepili i loaʻa

PAUKU 13: Noonoo hoopau

13.1 Nā hana hoʻolei

Huahana

Hiki ke hoʻokuʻu ʻia ka mea ma ka lawe ʻia ʻana i kahi mea kanu hoʻopau kemika i laikini ʻia a i ʻole ma ka hoʻomalu ʻia ʻana me ka holoi ʻana i ke kinoea. Mai hoʻohaumia i ka wai, nā meaʻai, nā meaʻai a me nā hua ma ka waiho ʻana a me ka hoʻolei ʻana. Mai hoʻokuʻu i nā ʻōnaehana sewer.

Puke i hoʻopaʻa ʻia

Hiki ke holoi ʻekolu i nā pahu (a i ʻole like) a hāʻawi ʻia no ka hana hou ʻana a i ʻole ka hoʻoponopono hou ʻana. ʻO kahi ʻē aʻe, hiki ke ʻoki ʻia ka pahu i mea hiki ʻole ke hoʻohana ʻia no nā kumu ʻē aʻe a laila e hoʻolei ʻia i loko o kahi ʻāina hoʻomaʻemaʻe. Hiki ke hoʻopau ʻia ka ʻā ʻana me ka flue gas scrubbing no nā mea hoʻopihapiha hoʻopau.

PAUKU 14: Kaʻike lawe

Helu 14.1UN

14.2UN inoa hoʻouna kūpono

14.3Papa ulia pōpilikia (es)

14.4 Puʻupuʻu pūʻulu, inā pili

14.5 Nā pōʻino o ke kaiapuni

14.6 ʻO ka mālama kūikawā no ka mea hoʻohana

ʻaʻohe ʻikepili i loaʻa

14.7 Lawe i ka nui e like me nā mea kani IMO

ʻaʻohe ʻikepili i loaʻa

PAUKU 15: ʻIke hoʻoponopono

15.1 Nā hoʻoponopono palekana, olakino a me ke kaiapuni no ka huahana i nīnau ʻia

PAUKU 16: Nā ʻike ʻē aʻe

ʻIke no ka hoʻoponopono

Nā pōkole a me nā acronyms

• CAS: Kemimi Abstracts Service
• ADR: ʻElepa ʻEulopa e pili ana i ka International Carriage of Dangerous Goods ma ke alanui
• RID: Hoʻoponopono e pili ana i ke kaʻa honua o nā waiwai weliweli ma ke kaʻaahi
• IMDG: Nā waiwai pōʻino moana o ka honua
• IATA: International Air Transportation Association
• TWA: Awelika Weighted Time
• STEL: Ka palena hoʻolaha pōkole
• LC50: Hoʻopaʻa make 50%
• LD50: ʻAha make 50%
• EC50: Hoʻopaʻa kūpono 50%
• IPCS – The International Chemical Safety Cards (ICSC), punaewele: http://www.ilo.org/dyn/icsc/showcard.home
• HSDB – Pūnaehana ʻikepili Hazardous Substances, pūnaewele: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
• IARC – International Agency for Research on Cancer, punaewele: http://www.iarc.fr/
• eChemPortal – ʻO ka Portal Global i ka ʻike e pili ana i nā mea kemika e OECD, pūnaewele: http://www.echeportal.org/echeportal/index?pageID=0&request_locale=en
• CAMEO Chemicals, punaewele: http://cameochemicals.noaa.gov/search/simple
• ChemIDplus, punaewele: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
• ERG - Puke alakaʻi no ka hoʻokō ʻana i ka pilikia e ka US Department of Transportation, pūnaewele: http://www.phmsa.dot.gov/hazmat/library/erg
• Kelemānia GESTIS-ʻikepili ma luna o ka mea pōʻino, pūnaewele: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
• ECHA - European Chemical Agency, pūnaewele: https://echa.europa.eu/

Nā kuhikuhi

Nā ʻike ʻē aʻe

Ma hope o ka hoʻopili ʻana me ka hoʻokumu ʻia ʻana o ka blister wai, hiki ke hoʻopaneʻe ʻia a hala kekahi mau hola. ʻAʻole ʻike ʻia nā palena pahū ma nā palapala, ʻoiai ʻo ka mea hiki ke puhi a loaʻa kahi kiko uila <61°C. ʻAʻole lawa ka hōʻike ʻana i ka hana. e kukakuka i ka mea akamai.

Kekahi nīnau e pili ana i kēia SDS, E ʻoluʻolu e hoʻouna i kāu nīnau iinfo@mit-ivy.com